• Graphical abstract: A strategy toward constructing a bifunctionalized MOF catalyst: post-synthetic modification of MOFs on organic ligands and coordinatively unsaturated metal sites

  • Scheme 1:The generic procedure for synthesizing bifunctional MOFs by grafting the functional groups onto both organic ligands and CUSs, respectively (grey ball: metal or metal cluster; orange pillar: organic ligand; green, and lavender bar: functional groups).

  • Fig.1 (a) FT-IR spectra of the dehydrated samples under vacuum;(b) FT-IR spectra of the as-synthesized sample with a KBr tablet. MIL-101 (black); MIL-101-NHBOC (red); MIL-101-SO3H-NHBOC (blue); and MIL-101-SO3H-NH2 (green).

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论文摘要

We report here a luminescent metal–organic framework [Zn3(TDPAT)(H2O)3] [TDPAT = 2,4,6-tris(3,5-dicarboxyl phenylamino)-1,3,5-triazine] exhibiting strong luminescence at room temperature, which can serve as the first case of a dual functional luminescent sensor for quantitatively detecting the concentration of nitrobenzene and temperature.

论文题目

A strategy toward constructing bifunctionalized MOF catalyst: post-synthesized modification of MOFs on organic ligands and coordinatively unsaturated metal sites

发表刊物
Chem. Commun., 2012,48 (49),6151-6153.B.Li, Y.Zhang, D.Ma, L.Li, G.Li, G.Li, Z.Shi*, S.Feng

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